Stabilization of Nitrous Acid

Stabilization of Nitrous Acid Abstract Nitrous acid (HNO2) was stabilized via supporting on Polyvinylpolypyrrolidone (PVPP) and the thermal stabilization and structure were estimated using thermogravimetric analysis measurement and spectroscopic methods, respectively. Some novel heterocyclic azo dyes were synthesized by selective diazotization of aromatic amines followed by coupling with some susceptible aromatic compounds. The stereochemistry structure of the synthesized dyes were optimized using B3LYP at 6-311 G(d,p) basis set and their electron excitation properties were evaluated using calculations of density functional theory. UV-Visible analysis was applied for Photophysical properties evaluation of the new dyes and compared with computed vertical excitation obtained from TD-DFT. Also, the azo-hydrazone tautomerism of the triazine azo dyes was investigated and the results show that for all of the synthesized dyes both azo and hydrazone tautomeric forms exist, while 3a-5 shows more notable hydrazone form than others. Keywords: Polyvinylpolypyrrolidone, Nitrous acid, Azo dyes, azo-hydrazone tautomerism 1. Introduction Nitrous acid as a weak inorganic acid has significant applications in organic reactions such as diazotization, nitrosonation and Sandmeyer Reaction,[1,2] but its instability in temperatures upper 5  °C causes some restrictions to using it. In this work, we stabilized nitrous acid via supporting on polyvinylpolypyrrolidone (PVPP) and then utilized it in synthesis of some novel azo dyes. However, PVPP has been reported as an efficient support in many cases such as trifluoroboride and nitric acid.[3,4] PVPP-HNO2 has many advantages that make it environmentally acceptable in both industrial and laboratory viewpoints. It is applicable for a long time after preparation and the polymer easily remove by washing with water. In particular, nitrous acid absorbed on polyvinylpolypyrrolidone takes part in azo coupling reaction and the polymer remains almost completely intact. However, the literature describing arylamines conversion to diazonium salts using polyvinylpolypyrrolidone supported nitrous acid (PVPP-HNO2) is not available. Herein, we wish to present a convenient procedure for diazotization reaction using this stable reagent. Azo colorants from aromatic heterocyclic amines have sublimation fastness, excellent light and color strength.[5] They are one of the important groups of synthetic organic dyes. They are applied in various fields such as electronic photography, liquid crystal displays, paper printing, bleaching, polymers, laser technology, dyeing, color formers, data storage and solar energy conversion.[6] They also have been known as antibacterial, antifungal and anti-tumor compounds.[7,8] The compound 1,3,5-triazine has an alternative six-membered heterocyclic ring with an equal number of nitrogen and carbon atoms.[9] The triazines are analogues of benzene rings, which makes them as an aromatic compound like benzene. 1,3,5-Triazine, a common reagent which is used as herbicides and pharmaceuticals.[9] The diazonium salts of triazines derivatives have been reported as a diazotization targets in the synthesis of a variety of heterocyclic azo dyes[10,11] but no report found in direct diazotization of triazines with more than one aromatic amine group. The existence of azo-hydrazone equilibrium in azo colorants having the hydroxyl group at ortho or para position to azo linkage was proved in 1983.[12] In hydrazone form, due to the hydrogen bonding, a coplanar six-membered ring is formed with higher thermal stability than azo form ones.[13] After reductive cleavage, the azo chromophoric system gives carcinogenic amines,[14] while in the hydrazone tautomer will be cleaved the C-N bond instead of N=N bond.[15] The study of azo-hydrazone tautomerism gives the great information for degradation of azo chromophores with least toxicological effect on the environment. Finally, we report preparation of polyvinylpolypyrrolidone supported nitrous acid (PVPP-HNO2) and synthesis of novel azo dyes by diazotization of 6-phenyl-1,3,5-triazine-2,4-diamine (1)and 1,3,5-triazine-2,4,6-triamine (2), followed by coupling with hydroxyl and amine substituted of aromatic compounds (Scheme 1). The absorption spectra were obtained using a UV-Visible spectrophotometer and the structures of the triazine azo dyes were confirmed by spectral analysis. Also, DFT calculation was used for study of their azo-hydrazone tautomerism. The structures in azo and hydrazone forms were optimized in the TD-SCF method using B3LYP/6-311 G(d,p) basis sets. 3. Results and discussions 3.1. Stabilization of HNO2 over PVPP PVPP-HNO2 was prepared by a simple route. As regards the nitrous acid is extremely unstable in temperatures over than 5  °C, polyvinylpolypyrrolidone which previously has been applied as an efficient support,[3,4] was used and the spectroscopic and experimental results showed that PVPP can stabilize nitrous acid by formation of PVPP-HNO2. Thermal gravimetric analysis (TGA) investigation of the polymer and PVPP-HNO2 was performed to study their thermal stability (Fig. 1). The thermal decomposition of PVPP starts at near 330  °C and a sharp burning of polymer chains in pure PVPP sample occurs between 360  °C with the weight loss of ~75% of the initial weight. TGA spectra of PVPP-HNO2 demonstrate a mass degradation at 70  °C in PVPP-HNO2, whereas there is no similar situation in TGA spectra of pure PVPP. In other words, TGA spectra of PVPP-HNO2 show that stability of nitrous acid has been increased to 70  °C.   Due to that, the probable hydrogen bonding causes the stability of nitrous acid via prevention of its decomposition to nitrogen oxides. Furthermore the results of acid-base titration show that the PVPP-HNO2 is clearly more acidic than pure PVPP. While pH of the 0.1% solution of PVPP in water is about 7.0, but the same of PVPP-HNO2 is about 2.92. In other word, [H+] is 1.2ÃÆ'-10-3 M and it shows that [HNO2] is about 0.0032 M and it reveals there is about 0.02 g of nitrous acid in 1 g of PVPP-HNO2 which shows good accordance with TGA results. PVPP-HNO2 was prepared in different ratios of PVPP and HNO2.The best result that showed the maximum capacity of acid in the polymer was 20% w/w. The ratios determined by acid-base titration was consistent with TGA degradation analysis. Besides, the synthesis of PVPP-HNO2 was confirmed by FT-IR spectrum. It shows carbonyl band at 1658 cm-1, whereas the same band in pure PVPP has appeared at 1668 cm-1. This can attribute to hydrogen bonding between nitrous acid and PVPP (Figure 2). This type of interaction has been reported between PVPP and polyphenols.[16] The existence of the N-O band stretching at 1380 and 1572 cm-1 in PVPP-HNO2 and absence of this band on PVPP, gives the indication that nitrous acid has been linked to PVPP polymer (Figure 3). 3.2. Synthesis and characterization of azo dyes A simple and facile synthetic route was presented for the preparation of triazine azo dyes. We found that these products can participate in azo coupling reaction to form various and already known azo dyes. Therefore, we treated diazonium salts with 1-naphtol, 2-naphtol and other amino and hydroxy aromatic compounds to obtain a variety of azo dyes in good yields. The compound 4-amino-6-phenyl-1,3,5-triazine-2-diazonium was synthesized from mixture of 6-phenyl-1,3,5-triazine-2,4-diamine (1)and PVPP-HNO2 in 1 mmol of diamine to 2.0 g of PVPP-HNO2 ratio and further coupled with 1 mmol of 2-naphthol in DMSO to obtain 1-((4-amino-6-phenyl-1,3,5-triazin-2-yl)diazenyl)naphthalen-2-ol (3a-2)in good yield. Other derivatives have been synthesized by different coupling components (Scheme 2). The chemical structure of the new dyes was confirmed by 1H and 13C NMR spectroscopy. 2-naphtholic dyes 3a-2 and 3b-2 contain the hydroxyl group at ortho-position to the azo bridge and have the susceptibility to make a six-membered ring due to intramolecular hydrogen transfer. The result of this type of interaction is chemical shift deshielding of hydroxyl group proton than usual. 1H NMR spectra summarized in Table 1 indicates the dye 3a-5 shows an extra singlet at ÃŽÂ ´ 12.11 ppm attributed to N-H proton which is in hydrazone form.   The protons of NH2 in the heterocyclic ring of series 3a show singlet peaks at ÃŽÂ ´ 8.16 to 8.63 ppm while the same at series 3b appear at ÃŽÂ ´ 6.77 to 6.99 ppm. The 13C NMR spectrum of heterocyclic ring carbons shows down field peaks at ÃŽÂ ´ 180-190 ppm. Except compound 3a-4 which have three non-aromatic carbons, all of the other compounds just have aromatic carbons. 13C NMR spectrum of 3a-4 shows two peaks at ÃŽÂ ´ 96.2 and 151 .3 ppm that attributed to the carbons which have been linked to azo group and the hydroxyl group, respectively and a peak at ÃŽÂ ´ 162.0 ppm which assigned as ester carbon of coumarin ring. Infrared spectra of the synthesized chromophores show the band at 1500-1570 cm-1 related to the N=N bond.   A unique band at 2200 cm-1 in 3a-5 reveals the existence of C=N group which can be another evidence for the existence of hydrazone form in this compound. Electron ionization mass spectroscopy (EI-MS) was used to verify structure of the synthesized azo dyes. The base peak in all of the dyes is due to fragmentation of the molecules in the azo bridge. Series 3a and 3b show a base peak at m/z 171 and 110, respectively which attributed to the ionized heterocyclic rings. 3.3. Photo-physical properties and solvent effects To find out the color properties with structural correlation of the synthesized azo dyes, UV-Visible spectra of the dyes were recorded in solvents such as n-hexane, ethanol, acetonitrile and dimethyl sulfoxide at concentration of ~10-4 M and at room temperature. The results are tabulated in Table 1. Although a moderate bathochromic shift in ethanol and acetonitrile was seen, but generally no significant bathochromic shift was observed.  Ãƒâ€šÃ‚   The UV-Vis absorption spectra of all of the dyes in all solvents show the main band at 290-330 nm which can be assigned to moderate energy transition of the aromatic ring. All of the 3b series and compounds 3a-2, 3a-4 and 3a-5 in all solvents, two bands are displayed arising from the à Ã¢â€š ¬Ãƒ ¢Ã¢â‚¬  Ã¢â‚¬â„¢Ãƒ Ã¢â€š ¬* transitions in the backbone. The second bands appear at 360-500 nm can be assigned to azo bridge or intermolecular azo-aromatic chromophore. 3.4. Computational study: Gaussian 03 program package was employed to study Time-Dependent Density Functional Theory (TD-DFT) and the profusion of the synthesized azo dyes in their azo and hydrazone tautomeric forms.[17] TD-DFT calculations were applied using B3LYP/6-311 G(d,p) basis set with the default convergence criteria and without any limitation on the geometry. The TD-DFT provide the most powerful and effective computational tool for examining the ground and excited state properties of the azo molecules compared with obtained UV-Vis data. Time-dependent DFT method was applied for determination of the UV-Vis spectra, electronic transitions, and vertical excitation energies. 3.4.1. UV-Vis spectral analysis The UV-Vis spectra of azo dyes molecules were measured in dimethyl sulfoxide solution as shown in Figure 4. The calculated absorption maximum wavelength (ÃŽÂ »max), electron transition energies and oscillator strength both in solvent phase (DMSO as solvent) along with recorded UV-Visible data are shown in tables 2 and 3. The main characteristic of the spectra is determined by the general structure of the molecules. Each molecule has a double band Nà ¢Ã¢â‚¬ ¢Ã‚ N (azo group) which is directly conjugated with a homocyclic and heterocyclic aromatic ring. This group has a wide electronic delocalization. Therefore, it is possible to predict the presence of the main absorption band associated to a à Ã¢â€š ¬-delocalized system that involves the fragment Nà ¢Ã¢â‚¬ ¢Ã‚ N and other associated internal transitions that emerge from the aromatic and/or heterocyclic system. In this sense and in according with the structure of the compounds, we can determine that the first absorption band ÃŽÂ »1 located in the range of 290-320 nm with low intensity that appears as shoulder is attributed to à Ã¢â€š ¬Ãƒ ¢Ã¢â‚¬  Ã¢â‚¬â„¢Ãƒ Ã¢â€š ¬* transition that involves the aromatic rings, while the second absorption band ÃŽÂ »2 located in the range of 300-400 nm, attributed to a à Ã¢â€š ¬Ãƒ ¢Ã¢â‚¬  Ã¢â‚¬â„¢ à Ã¢ ‚ ¬* transition. This transition involves the azo bridge. The remaining absorption band located at lower energy corresponds to ÃŽÂ »3 and is assigned as the type nà ¢Ã¢â‚¬  Ã¢â‚¬â„¢ à Ã¢â€š ¬* transition. A similar behavior of the previous transition is observed. In tables 2 and 3, the experimental and calculated maximum absorption and the corresponding orbital contribution are shown. As observed, shorter wavelengths (ÃŽÂ »1) and in some cases ÃŽÂ »2 belong to lower occupied MOs such as HOMO-4, HOMO-6 and HOMO-8 and LUMO while longer wavelengths (ÃŽÂ »3) involves frontier molecular orbitals (FMOs). The description of FMO will be discussed in the DFT section. An example of the involved MOs for compound 3a-2 is presented in Figure 5. The entire former assignations were corroborated using TD-DFT calculations. The involved MOs for all of the synthesized compounds are presented in Figure S1-9. 3.4.2. DFT calculations For prediction of the molecules electronic spectra, the TD-DFT calculation is used because of low computational cost and high accuracy. The electronic structure of the molecule in ground state can be determined from the wave function of the electron moving within molecule because molecular orbital can be treated as electron channels.[18] The Gauss View program is applied to calculate group contribution of molecular orbitals, i.e. the highest occupied molecular orbitals (HOMOs) and lowest unoccupied molecular orbitals (LUMOs). In almost every calculated transitions, the FMO are involved, vide supra. The FMO of all compounds shows similar characteristics as observed in supplementary data (Fig. S1-9). In all cases, HOMO is delocalized over the homo-aromatic ring and azo bridge. The HOMO-1 is composed in every case mainly by the azo bridge. In terms of unoccupied MOs, the LUMO is mainly centered over the homocyclic and heterocyclic aromatic rings and azo bridge. On the other hand LUMO+1 of naphtholic compounds 3a-1, 3a-2, 3b-1 and 3b-2 is located almost over the triazine ring while in other compounds, LUMO+1 attributed to non-triazine aromatic rings. The ionization potential (IP), electron affinity and GAP energies do not follow any trend and the calculated values are similar and do not depend on the substituted coupled to triazine rings.[19] The estimated reactivity indexes such as chemical potential (ÃŽÂ ¼), chemical hardness (ÃŽÂ ·) and electrophilicity (à Ã¢â‚¬ °) are reported for make the approach of the potential reactivity of these synthesized dyes (Table 4). Chemical hardness is a measure of the resistance of chemical species to change its electronic configuration.[19] It is an index of the stability and chemical reactivity of compounds. The highest value of ÃŽÂ · is shown by compounds 3a-5 and 3b-4 in 3a and 3b series, respectively, which have 2-nitroaniline as coupling aromatic agent and are the most electron attracting substituent. On the other hand, the smallest value is shown by 3a-2 and 3b-2 which have 2-naphtol in the structure as a good electron-donor substituent. Chemical potential characterizes the tendency of escaping of electrons from the equilibrium system.[19,20] This index shows an opposite behavior to that of ÃŽÂ ·, where the highest value belongs to 3a-2 and 3b-2 which have electron donor substituent and the smallest value is shown by 3a-1 and 3b-4 which the second compound acts as an electron acceptor substituent while the first can acts as an electron acceptor via induction. Electrophilicity index (à Ã¢â‚¬ °) c ould give information comparing two in which one is nucleophile/electrophile via lower/higher à Ã¢â‚¬ °.[20] For example comparing between 3a-1 and 3a-2 shows that 3a-1 has higher à Ã¢â‚¬ ° and it can attribute to more electron attraction of 4-hydroxy substituent rather than 2-hydroxy in the naphtholic system. Another attractive comparison between 3a-1 and 3b-1 shows more electron attraction in triazine ring in 3a-1. A phenyl group which replaced with the amine group has increased electrophilicity of 3a-1 than to 3b-1. Although some contradictions are found in case 3a-5 that it can appropriate to azo-hydrazone tautomerism that it will be discussed in the tautomerism section. 3.4.3. Optimized geometries of azo-hydrazone tautomeric forms The optimized ground state geometries of the dyes in azo-hydrazone tautomeric forms are shown in figures 6 and 7. Figure 7. Ground state optimized structure of dyes 3a series in their azo and hydrazone tautomeric forms Optimized ground state geometries of the compounds in azo forms are almost planar such as 3a-1 and 3a-2 which show a mild dihedral angular twist less than 5 ° at N15-N14-C11-N12 and at N7-N14-C9-C14. All hydrazone forms show a dihedral angle twist by near 30 ° which follows no trend. Optimized bond lengths of the synthesized triazine azo dyes (3a and 3b) have been calculated. The O-H bond lengths of azo forms for all of the naphtholic series (3a-1, 3a-2, 3b-1 and 3b-2) is 0.960 Ã…. Similarly, the N-H bond lengths are 1.015 Ã… for 3a-1 and 3a-2 and 1.000 Ã… for 3b-1 and 3b-2. This calculated information shows no significant trend to determine azo-hydrazone tautomerism but the obtained N-N bond can signify the single-double bond character of the bond. The N-N bond length in hydrazone form falls shorter to the model value of 1.400 Ã… for single bond.[21] N-N bond length in 3a and 3b azo series are 1.232 Ã… and this bond length in 3a and 3b hydrazone forms are 1.400 Ã… except in 3a-5 which N-N bond length in hydrazone form is 1.330 Ã… and this confirms our 1H NMR observation in the existence of 3a-5 in both azo-hydrazone forms in significant ratio, while in other compounds this rate of ratio is not impressive. 3.4.4. Calculated energies of azo-hydrazone tautomeric forms The free energies (E/hartree) and relative energies (ΆE/ kJmol-1) of the synthesized dyes in both azo and hydrazone forms calculated using the B3LYP/6-311G (d,p) level to check theoretical stability difference between tautomeric forms and the values tabulated in Table 5. Contrary to this expectation that hydrazone forms have relative stability than azo tautomers,[15,22] in our TDDFT calculations, only hydrazone form of 3a-1 shows more relative stability than the same of azo form by 26.26 kJmol-1. 2-naphtholic dyes 3a-2 and 3b-2 show a significant stability in azo forms than hydrazone forms by 1260.48 and 498.94 kJmol-1, respectively. In the other compounds there is no difference between the stability of azo and hydrzone form and it shows that in comparison to experimental data, there is no notable accordance in TDDFT structures energy. 4. Conclusion In summary, we have successfully developed an efficient protocol to stabilize nitrous acid by supporting on polyvinylpolypyrrolidone (PVPP). Synthesized PVPP-HNO2 confirmed by simple titration and FT-IR analysis. The TGA results show that the supported system has acceptable thermal stability. In the following, we have synthesized nine heterocyclic triazine azo dyes and they were confirmed by FT-IR, 1H NMR, and mass spectral analysis. UV-Visible spectral analysis was compared with calculated data. TDDFT calculations were performed showing enough adaption with experimental observations. The optimized structure of azo and hydrazone form using B3LYP/6-311 G(d,p) basis set of calculation shows that azo is more stable form in all of the synthesized dyes except 3a-5, which exist in both azo and hydrazone forms. Acknowledgement.   We are thankful to the Yasouj University for partial support of this work. References T. Turney, G. Wright, Chem. Rev. 1959, 59, 497. N. Suzuki, Y. Kaneko, T. Nomoto, Y. Izawa, Chem. Commun. 1984, 22, 1523. M. Mokhtary, S. Refahati, Dyes Pigments 2013, 99, 378. M. Nogami, Y. Sugiyama, T. Kawasaki, M. Harada, Y. Morita, T. Kikuchi, Y. Ikeda, J. Radioanal. Nucl. chem. 2010, 283, 541. H. S. Bhatti, S. Seshadri., Color. Tech. 2004, 120, 151. M. Ghasemian, A. Kakanejadifard, F. Azarbani, A. Zabardasti, S. Shirali, Z. Saki, S. Kakanejadifard, Spectrochim. Acta A. 2015, 138, 643. I. M. Awad, Phosphorus Sulfur 1996, 114, 17. G. Powis, M. Seewald, D. Melder, M. Hoke, C. Gratas, T. Christensen, D. E. Chapman, Cancer Chemoth. Pharm. 1992, 31, 223. W. Hua, E. R. Bennett, R. J. Letcher, Water Res. 2006, 40, 2259. M. A. Satam, R. K. Raut, N. Sekar, Dyes Pigments 2013, 96, 92. D. R. Patel, K. C. Patel, Dyes Pigments 2011, 90, 1. A. LyÄ ka, Collect. Czech. Chem. C. 1983, 48, 3104. Y. Do Kim, J. H. Cho, C. R. Park, J. H. Choi, C. Yoon, J. P. Kim, Dyes Pigments 2011, 89, 1. H. Pinheiro, E. Touraud, O. Thomas, Dyes Pigments 2004, 61, 121. P. G. Umape, V. S. Patil, V. S. Padalkar, K. R. Phatangare, V. D. Gupta, A. B. Thate, N. Sekar, Dyes Pigments 2013, 99, 291. K. J. Siebert, P. Y. Lynn, J. Agr. Food. Chem. 1997, 45, 4275. M. Frisch, G. Trucks, H. Schlegel, G. Scuseria, M. Robb, J. Cheeseman, Gaussian 03, revision C. 02 2008. G. W. Drake, Springer handbook of atomic, molecular and optical physics, Springer Science Business Media 2006. R. G. Pearson, J. Mol. Struc-Theochem. 1992, 255, 261. P. K. Chattaraj, S. Giri, Annu. Rep. Prog. Chem., Sect. C: Phys. Chem. 2009, 105, 13. Y. Ebead, Dyes Pigments 2012, 92, 705. M. S. Deshmukh, N. N. Sekar, Can. Chem. Trans. 1, 2013, 305.

Baque-Manalang Dental Clinic Online Reservation Essay

Introduction The use of online services nowadays becomes more necessary in the various fields. It is because of the advantage and useful effects to many people when it comes to online reservation because our society is facing rapid growths of need, availability and development of different commercial web-based application. The online reservation services differ from the traditional mode in the capacity to provide services regardless of temporal and spatial constraints. They are also different from traditional interpersonal services that are delivered face-to-face. It allows persons to employ Information Technology without being tied to a single location. This technology enables users to access the site at any time in any location. A suitable use of the online reservation services and wireless technology allows new application, management and reservation for dental clinic via online services. The objective of online reservation is to reduce the effort and the time for the customers to set appointm ent and to receive services and improved the reservation validation efficiency. Background of the study Baque-Manalang Clinic is a dental clinic located at Hilario St., Ligtasan, Tarlac, Tarlac. It is owned by Dr. Eillen B. Manalang, DMD, established since 1992. The said clinic is operated by one dentist, two dental assistants, one dental photographer, four front desk staff, and one dental technician. It offers teeth maintenance, enhancement techniques and cosmetic dentistry services. The clinic’s operating hours is 8:00 AM to 5:00 PM on weekdays and 10:00 AM to 5:00 PM on Saturdays. Daily they are accommodating an estimated 15 to 20 patients from Tarlac and nearby provinces. Despite its popularity, the said clinic is still using traditional reservation system. Statement of the Objective Despite its popularity, the said dental clinic is still using traditional reservation system which is time consuming and prone to problems like long waiting line and crowded queue. So in line with it, the following objectives are enumerated to cognate the problems. Specifically, it aims to accomplish the following: 1. To design and develop an online reservation system that aims to strengthen the weakness found in existing traditional reservation system. 2. To validate the developed system in terms of: 3.1. Effectiveness and efficiency 3.2. User friendliness 3.3. Security of data 3. To determine the proposed system feasible through Cost Benefits Analysis. Scope of the Study The scope of this study will focus on the patients, who will use the system to make the appointment via online service. The prototype can be used by the staff and dentist to manage the appointment for the dental clinic via online system for those who would like to set an appointment anytime, anywhere. This study is mainly focused on providing a website for Baque – Manalang Dental Clinic. The said website includes: * Online reservation or scheduling exclusively for registered patients. * Clinic information – address, site map, profile of dentist, etc. * List and price of services offered and the time allotted for services to be consumed. * Services-directory where the patients can view the information about the preferred service to take. * Information and tips on how to prevent dental problems. Delimitations The proponents limit this study for Baque – Manalang Dental Clinic only. Only current patients with previous transactions are given with accounts for the online reservation system. Only trained personnel can conduct the site maintenance of the proposed system. Significance of the Study This study is viewed to be valuable to following: Clinic. The proposed system will simplify and automate the clinic task inline with reservation to provide the clients with better service. Dentist and Staff. The proposed system will help the dentist easily identify the patients as scheduled online. Patients. The proposed system will help patients reduce their waiting time and provide them assurance to be accommodated as scheduled online. Definition of Terms In order to provide an adequate channel of communication between the researcher and the readers, the following terms arranged alphabetically and defined conceptually. Access. Access is to obtain entry to a particular program; with records and network entry procedure. Computer. Machine that performs a wide variety of activities with reliability, accuracy, speed and tasks, such as mathematical calculations or electronic communication, under a control of a set of instructions called a program. Internet. A means of connecting a computer to any other computer anywhere in the world via dedicated routers and server. Online. Activated and ready for operation; capable of communicating with or being controlled by a computer. Prototype. An original, full-scale, and usually working model of a new product or new version on an existing product. System. Any collection of component elements that work together to perform a task. Website. The file of information located on a server connected to World Wide Web (WWW). It includes text, photographs, illustrations and video, music and computer programs. It also often include links to other sites in the form of hypertext, highlighted or colored text that the user can click on with their mouse, instructing their computer to jump to the new site. Reservation System. A system that involves the process of reserving and booking of appointments on a specific date and time. CHAPTER 2 Review of related Literature and Studies This chapter presents a review of conceptual literature which is supported by studies relevant to this study. The review of literature focuses on online reservation for Baque-Dental Clinic. Related Literature Foreign Eric Richard (2012) .Consumers these days almost expects an online presence from a company or business. In fact, they may look past businesses that are not online or consider another provider. Convenience is a big factor in an individual’s decision-making process, and not offering customers what they want can put a business at a big disadvantage, especially if their  competitors offer this benefit. Convenience plays a big role in our â€Å"24-7† world. Many people simply do not have the time to pick up a phone during business hours to book an appointment. Some would much rather go online and schedule it when it’s most convenient for them. Online scheduling software makes it easy to accomplish this. Once a business sets up its scheduler, it can then add a button or link on its Web site for customers to access its online scheduler. Once on the scheduler page, customers typically can view and select available appointment or reservation times and dates, as well as other information such as services and specific staff members. Depending on internal preferences set by the business operator, the scheduler may also require the customer to register to use the service. Even businesses without a Web site can implement online scheduling into their operations. Once a business creates an account and scheduler, the service will issue it a URL link. In essence, the scheduler itself is a Web site. Entering this link in a Web browser will take a user directly to the scheduling application. Businesses can simply provide this link to customers. Eric Richard (2012) .For many service oriented business, accurate and timely reservations are necessity to ensure proper service and a positive customer experience. From tour operators and boat rental providers to managers of athletic fields and facilities, these groups must have a proven reservation system in place, not only for internal scheduling processes, but also for the convenience of their customers. Traditional reservation procedures often come up short in both regards. And it’s for these reasons that many business, organizations and individuals are incorporating online reservation systems into their operations. Booking and managing customer reservations, although a vital component of many service-based groups is generally viewed as time-consuming and tedious. The traditional manner of scheduling reservations doesn’t help refute this statement: It usually involves booking reservation over the phone and by e-mail, then recording and managing the dates, times, services and customer contact information in separate appointment books, files, spreadsheets or folders. Not only does this method require a considerable amount of staff time, it also does not give customers the ability to book their reservations when it’s most convenient for them. Many individuals simply do not have the time to call in a reservations or appointment during normal business hours. This can lead to two different scenarios: The person  can either book the reservation online (if the service provider offers this option), or he or she can leave a voice message, in which case the provider must take the time to follow up with the individual (and possibly engage in a game of â€Å"phone-tag† until a specific reservation time is agree upon). Most will agree that the former is the more appealing of these two schemes. An online reservation system is generally the best option for these service-providers to automate and improve their booking processes. Commonly referred to as Software as a Service (SaaS) and cloud-computing applications, this technology is accessible through any Internet connection and typically does not require any installations, downloads or expensive hardware. SaaS is software delivery method that provides access to software and its functions remotely as a Web-based service. Software as a Service allow organizations to access business functionality at a cost typically less than paying for licensed applications since SaaS pricing is based on a monthly fee. Also, because the software is hosted remotely, users don’t need to invest in additional hardware. Software as a Service removes the need for organization to handle the installation, set up and often daily upkeep and maintenance. Software as a service may also be referred to a simply hosted application. Both the service provider and its customers access is in the same manner as any Web page. Like online data storage and document uploads applications, online reservation systems are securely housed online and not confined to an individual computer terminal or network. This characteristic not only makes it possible for customers to book reservations online, it also give service providers and their staff the ability to access their reservation calendar and customer details from any Internet connection, a valuable benefit for those individuals who must have access to this information from outside their office. Booking customer reservations with a pen and paper appointment book simply doesn’t cut it in today’s busy, 24-7 world. Technology has caught up with all office procedures, including booking processes, and service providers that tap into these online reservation systems can expect a significant improvement in their overall operations. And on top of that, they’ll have more satisfied customers. Local Alice Adams (2011).Kabayan Hotel Cubao has recently integrated a reservation  system in its website for a more efficient online booking. Through this technology, travellers worldwide save time and effort in reserving accommodations as the user-friendly booking engine makes the whole process a simple and effortless activity. Online hotel reservations are becoming popular method for booking hotel rooms, and Kabayan Hotel Cubao takes this opportunity to ensure fast reservations for guests from different parts of the world. This easy-to-use system, powered by DirectWithHotels, is now fully functioning at its website, http://www.kabayanhotel.com.ph/cubao.php. With this, guest only have to go through a very short booking process to be entitled of a comfortable stay at this budget hotel. Upon clicking the â€Å"Reserve Now † button, visitors can immediately select arrival and departure dates, navigate their way to their preferred guestrooms, and view the inclusive amenities and room rates. And after paying a 10% deposit, which is certified by Trust wave and secured by VeriSign, they instantly receive confirmation directly from the hotel via e-mail. With just a few clicks of the mouse, guests are guaranteed to experience amazing ease and warm Filipino hospitality at this budget hotel in Quezon City, Philippines. Manila Bulletin Publishing Corporation (2012). BooktoEat.ph now offers the opportunity to book restaurants online, in real-time just like booking in a hotel or an airline. The days of waiting hours for a restaurant to open, call back, respond to an e-mail or a telephone message will soon be over. A real-time reservation completely automates the reservation process. When making a reservation using BookToEat.ph the reservation is instantly confirmed in the restaurant’s Electronic Reservation System. This is the same Reservation System that used by the restaurant to manage all of its bookings so it automatically checks for real-time availability. The difference between BookToEat.ph and most other restaurant reservation services that we are genuinely â€Å"real-time† so no more busy signals, waiting until the restaurant opens or waiting hours for an e-mail response. BookToEat.ph now allows you to book your favourite restaurants on online in real-time just like booking in a hotel or an airline. The soon introduction of real-time bookings into Philippines presents a significant development for the restaurant industry. The concept has been hugely successful in the USA and UK markets, and in 2008 over 36 million bookings were made online in real-time. Related studies The application of modern information technology dominated so far by the use of internet websites and online reservation systems, gives competitive advance to other with same establishment. However the potential competitive advantage can be transformed into real advantage if only the websites have proper design. As a result, the advocator conducted research on the facts related to the system that might be helpful to its development. Foreign StormSource (2002).An online reservation system has booked over 50 million appointments and reservations since its launch in 2002. Over 4,000 businesses throughout the United States, Canada and 10 other countries rely on the software for such tasks as online reservation system of customer services, booking rooms, facilities and equipment, accepting online payments, sending reminders, and e-marketing. Scottsdale, Ariz.-based technology firm specializing in the development of online appointment software for a wide variety of applications and industries. Geared primarily toward small businesses such as doctors’ offices, spas, health clubs and massage therapists, users of Appointment-Plus also include Fortune 500 companies; colleges and universities; healthcare agencies and facilities; federal and local government; and freight and delivery services. Scharl, Wà ¶ber and Bauer (2003).Evaluate the effectiveness of hotel websites. Authors identify personal, system and media factors that contribute to hotel website adoption. In the system factors group, that is more controllable by the hotel management compared to personal and media factors, they identify the perceived utility of the product, speed of the system, intelligence, layout, services, navigation, interactivity, reliability of the system. Michael Pearce (2012). The online program at ksoutdoors.com – click on â€Å"reservations† – is part of the Reserve America system, which is used by about 20 states and 30 private groups to help customers reserve camping spots. Reservations for Kansas parks also can be made by calling 620-672-5911. The new system gets money into state park coffers quicker, and also saves time that the state park staff would have spent handling the money. Those are huge benefits for the department, which is constantly battling budget and staffing issues. Lanterman said it also allows the department to better study the demographics of its users. Adjustments can  then be made to make sure the public is best served. Wilson State Park is getting the most online reservations; Cheney and El Dorado State Parks are about tied for second place. Lanterman said usually no more than about half of the camping spots can be reserved online. The rest are first-come, first-served, as they have been for years. She said a few campers have been frustrated to arrive at a park and see their favourite site empty but reserved by another camper. Park managers, though, say support for the reservation system is strong and growing. â€Å"People like that they can go online, reserve the site they want, and when they show up it’s ready,† said Ryan Stucky, Cheney State Park manager. â€Å"Most are figuring out the system and that it’s more convenient for them.† Local Studies â€Å"An online inquiry and reservation system with virtual tour for La Maja Rica Hotel and Restaurant Tarlac City† a thesis conducted by Duenias, Kathleen Joy J., Ilagan, Keneth D. and Tolenceda, Niccolo Andrei P. AMA Computer College Tarlac City (March 2010), allows management for their hotel and restaurant to be more organized in terms of reservation, inquiry and customer avail of the available services and inquire for the details even without personal appearances which they can spare time, money and efforts. The Thesis entitled â€Å"Online Cagayan Valley Economic Zone Authority Information System† by Anwar Saludsong (April 2002), discuss the advantage of web-based application to allow user acquire information through online that is accessible through any internet. â€Å"Luisita Gold And Country Club Online Reservation† a Study conducted by Rina Lyn C. Burgos and Rowena S. Cortez at AMA Computer College Tarlac City (Aug 2005) discuss the capabilities of the internet and modern application to update users about the advantage and reliability of features of an online reservation system.A real-time reservation that completely automates the reservation process and reduce the effort and the time consume of customer. Theoretical Framework The proponents proposed system is a program that has a set of elements that work together to understand some objective that will help the Baque- Manalang Dental Clinic with regards to their manual reservation. One of the problems in most clinics nowadays is how to accommodate and serve  as many patients as possible, where patients do not need to go to the clinic for appointment scheduling. An online reservation system is generally the best option for these service-providers to automate and improve their booking processes. Not only that, this will also avoid patients not to experience a longer waiting time. Online reservations also assure the availability of schedule as these are shown online and security of information is provided. The literature has its similarity to the proponents propose system in the sense of both project utilize the internet function such as the availability of date and time which is one of the features that the proponents included in the study. The proponents are looking forward that the propose system will improve the manual reservation of the Baque- Manalang Dental Clinic. Conceptual Framework Below is the research paradigm which states the input data that will process to produce an output. Research, works, books, interviews, publication, net-surfing and studies are the researches mean gathering and compiling information and data that can help in the investigation improvement and development of the system

How the Beatles Changed a Generation

Ali GreerResearch PaperHST 367 How One Band Changed a Generation The 1960’s is a decade remembered for its counterculture, social revolution and an emergence of a new kind of popular culture. If you asked me what my first thoughts were when I hear the decade 1960s, I automatically think about the Beatles. Has a decade ever had such a defining musical group that represents not only a shift to more rebellious music such as Rock n Roll, but an influence so great that they are still talked about to this day?The Beatles not only changed music but they affected culture in ways that had not been challenged by a musical group before. I asked my mom what she remembers about the Beatles. She was only 6 when they performed on the Ed Sullivan Show but she still remembers. She said that, â€Å"The Beatles didn’t define a generation, they created one†. The first way that the Beatles challenged everyday popular culture was that the fact that they were British. Before the Beatle s traveled across â€Å"the pond†, the U. S. had been a tough break for aspiring British pop groups.The Beatles wanted to teach the world that pop music could be intelligent and that British groups could do that just as well as American music groups. Some could argue that the Beatles did not start a phenomenon, they somehow perfected the cultural significance of 1950’s musicians before them like Buddy Holly and Elvis Presley. Before settling with their signature rock sound, The Beatles started in the Skiffle genre, a type of music with jazz, blues and roots influences. By 1960, Lennon wanted to move away from Skiffle to more of a Rock n Roll sound.Lennon and McCartney perfected their writing skills and relied less and less on on outside material. This was a groundbreaking ideal in the music industry and it had a lasting impact on culture. It urged other big name music acts such as the Rolling Stones to start writing their own music. Lennon and McCartney would eventuall y become one of the most famous songwriting partnerships in music history. The Beatles first appeared on American television on February 9, 1964 on The Ed Sullivan Show. 40 % of the country, about 73 million viewers tuned in to see Paul, John, George and Ringo perform for the first time in America.This is still considered one of the most important moments in television history. Now one may ask, how did so many people know about this little band from Britain? The record I Want to Hold Your Hand was leaked in advance to American radio stations. The record label could not prevent DJs from the playing the record therefore the album was officially released on December 26, 1963. 250,000 copies were sold in the first three days of its release. It’s unclear who actually leaked the record beforehand, but this publicity stunt was hugely successful for the Beatles.Mobs of people were waiting for the Beatles when they arrived at JFK airport. When asked how did you find America, Ringo Sta rr jokingly said â€Å"Turn left at Greenland. † The media took to covering this frenzy as best as it could. Newsweek printed an article on February 24 ,1963 reviewing the Beatles’ performance on The Ed Sullivan Show. The last paragraph ended with this, â€Å"the odds are they will fade away, as most adults confidently predict. † No one could predict the upcoming effects that the Beatles would have on American culture. The Beatles had arrived in America during a confusing time.President Kennedy had been assassinated just a few months prior, the threat of a war in Vietnam was eminent and Americans needed something new. And the Beatles were just what they needed. They rejuvenated pop music for Americans. They were seen as modern and sleek. â€Å"Beatlemania was so strong because the times and the youth of America were simpler and more naive. † This simplicity of society would play a big role in the Beatles influence on culture because it would allow them to change their style so freely without doubt from the nation.Society would accept it as popular no matter what. When the Beatles arrived in America, parents of teenagers hated them. They hated their relationship themed lyrics, their sex appeal, etc. The Beatles influenced a generation to not do what their parents told them to and helped Rock n Roll gain its rebellious reputation. Naturally, The Beatles are best known for their music. Not only did they have a large number of hit songs, but their music also evolved very rapidly through the group's brief career, embarking on territory not previously explored by pop music groups.Released in 1967, â€Å"Sgt. Pepper's Lonely Hearts Club Band† was a huge breakthrough album in pop music with its use of orchestras, harpsichords, circus sounds and other effects that were largely created in the studio. No longer did pop groups just have to be guitars, a bass, drums and vocals — nor were they limited to what could be performed live . The Beatles still influence music years after their breakup. â€Å"Beatlesque† is â€Å"a term used by critics to describe music that has one or more traits or characteristics of the music made by the Beatles. There are also hundreds of Beatles tribute bands out there paying tribute to the Fab 4. â€Å"The Beatles sold a lot of records not because they were the greatest musicians but simply because their music was easy to sell to the masses: it had no difficult content, it had no technical innovations, it had no creative depth. They wrote a bunch of catchy 3-minute ditties and they were photogenic†. The Beatles were immensely popular during the 1960s and they helped feminize a culture. The baby boom began in 1946 and ended in 1964 which meant that ? f the nation’s population was in the teen or pre teen bracket. When the the Beatles appeared on The Ed Sullivan Show, hundreds of teenage girls were lined up, screaming. An important factor to Beatlemania was the fans. There was something slightly feminine about the Beatles. Their slightly tousled hair, their tailored suits. The Beatles had the perfect mix between masculinity and femininity. The Beatles persistent feature of women and love in their songs left teenage girls swooning and a culture that was more sexually driven than ever.As Steven Stark points out in his book Meet The Beatles, they also â€Å"challenged the definition that existed during their time of what it meant to be a man. †   Ã‚  Ã‚   â€Å"The Beatles were not only selling records, they were selling trends. † Featured in the Time All Time 100 Fashion Icons, the Beatles were always evolving when it came to style. You could say that it’s normal for musicians to change their appearance to keep up with society and the latest trends. The Beatles were the trend. Whatever they did, society copied. When the Beatles first traveled to America, they wore black collarless suits.They even popularized a haircut called the â€Å"moptop† The moptop was a straight cut, collar length in the back and over the ears on the sides. The public went crazy for this cut. McCartney writes in a letter, â€Å"George explained in a 60s interview that it was John and I having our hair cut in Paris which prompted him to do the same†¦. We were the first to take the plunge. † The Beatles were not afraid of taking risks. They took what they liked from popular culture and took it to a new extreme. Towards the end of Beatlemania, the Beatles embraced more of a psychedelic style, with bright patterns and colors.They even let their signature hairstyles grow out and even experimented with facial hair. John Lennon even established his own trend, wearing tea shade glasses which ended up being called â€Å"Lennon† glasses. The Beatles were not hesitant when it came to change, even when it dealt with changing their own fads and this is important to their success as culture icons. The Beatles di d not merely stay in the music industry. They dabbled in the movie business too. Their film, Yellow Submarine was a colorful trendsetter in the world of animation. Producers used techniques that had never been used before.Although Yellow Submarine was produced on a small budget, the film was met with mostly positive reviews. Talking about the film, Time Magazine stated that it, â€Å"turned into a smash hit, delighting adolescents and esthetes alike†. The aftermath of Yellow Submarine was that animation was being taken as a more serious form of art. Previously, animation had been described as silly or goofy. The Beatles changed this perspective. Josh Weinstein, a former writer for the animated series The Simpsons wrote an article describing how Yellow Submarine affected modern animation today.Weinstein states, â€Å"Without Yellow Submarine there would never have been The Simpsons, no Futurama, no South Park, no Toy Story, no Shrek No animated anything that enables us to lau gh at ourselves while being highly entertained. †   As you can see, The Beatles accomplishments in popular culture are still talked about today. The religious allure of the Beatles was a vital factor in allowing the group to endure. John Lennon was onto something in 1966 when he compared the group’s popularity with that of Jesus Christ.Multitudes flocked to them and even brought sick children to see if the Beatles could somehow heal them. Thus, those who have seen elements of religious ecstasy in Beatlemania are not wrong. â€Å"Religion, it must not be forgotten, has its roots in spiritual bonding. And the Beatles had a powerful appeal to a generation in calling forth a spiritual bonding. It was so intoxicating that it created mass hysteria. In this way, the Beatles—especially with their elevation to a kind of sainthood—have become modern counterparts to the religious figures of the past†.John Lennon once stated that, â€Å"The Beatles are more popular than Jesus† and this remark caused quite the controversy in the United States. It led to fans to protest the band and to burn their albums. This was different than the attitudes of society during Beatlemania. Society was actually challenging something the Beatles did. This was a momentous event because it showed that the Beatles were immune. They made mistakes too. They didn’t have a perfect image. But that lack of perfect image was the catalyst to the Beatles success. Society saw the Beatles as four men trying to change he face of music. The Beatles did not only influence religion, but political views as well. Lennon in an interview to Rolling Stone talks about the song â€Å"Revolution†, â€Å"I had been thinking about it up in the hills in India. I still had this ‘God will save us' feeling about it, that it's going to be all right (even now I'm saying ‘Hold on, John, it's going to be all right,' otherwise, I won't hold on) but that's why I did it, I wanted to talk, I wanted to say my piece about revolution. I wanted to tell you, or whoever listens, to communicate, to say ‘What do you say? This is what I say. † Revolution was the Beatles first overtly public political song. Revolution dealt with the War in Vietnam. New Left publications called the song a â€Å"betrayal†. Besides it blatant political undertones, Revolution went on to become a hit single. The Beatles were and still are so successful because of their infiltration of different media outlets. Music, television, movies, magazines, radio, etc. They knew that they needed not only to sell music but to sell a legacy. The Beatles influenced a whole generation during the 1960s and they are still influencing new generations to this day.This multi decade success is a clear example of their powerful grasp on American culture during the 1960s. Bibliography http://www. guardian. co. uk/film/2012/nov/19/beatles-yellow-submarine-simpsons-shrek http:// www. edsullivan. com/artists/the-beatles/ http://www. beatles-tribute-band-uk. co. uk/history. htm http://www. time. com/time/specials/packages/article/0,28804,2110513_2110627_2110708,00. html http://www. scaruffi. com/vol1/beatles. html#sgt http://beatle. wordpress. com/2008/08/23/history-the-beatles-started-a-revolution-that-changed-us-all-forever/ http://www. thebeatles. com/

Humanities - 11870 Words

MODULE 1: INTRODUCTION This module provides an overview on the subject of art appreciation for those entirely new to the subject. This is a complex topic to deal with and it is impossible to have a truly comprehensive discussion on the topic in such a brief essay. The student is advised to consult more advanced texts to gain further understanding of how to appreciate art more fully. HUMANITIES: What is it? †¢ The term Humanities comes from the Latin word, â€Å"humanitas† †¢ It generally refers to art, literature, music, architecture, dance and the theatre—in which human subjectivity is emphasized and individual expressiveness is dramatized. HOW IMPORTANT IS HUMANITIES †¢ The fields of knowledge and study falling under†¦show more content†¦Many people think art is subjective. The answer is: yes, it is. At the same time, however, there are still yardsticks we can use to measure the quality of the art, especially among works that belong to the same genre. To understand how this works, let us use a simple analogy. If you come from a foreign land and have never eaten char kway teow (fried flat rice noodles), the first time you try the dish, you may not be able to tell whether it is good or bad. But after youve tried the dish from ten different stalls, you will probably be able to tell which is better, and you probably would be able to define what qualities make for a good plate of char kway teow. Therefore, in order to know good art when you see it, you need to have seen a lot of art - both good and bad - in order to make the comparison. The fact is that mankind has been producing art for so long that the overall body of knowledge on art has become so complex that ordinary people cannot comprehend the scope of the subject without some form of structured education. Most people, however, continue to attempt to appraise art without investing the time and energy needed to understand the subject first. The way to learn how to art appreciation is to look at more good art. InShow MoreRelatedThe Humanities And Its Impact On Education Essay1750 Words   |  7 Pagesinstitutions are cutting the humanities from curricula. According to Nussbaum, our nation and those like it are economically hungry and are pushing technical careers instead. She disputes that a decrease in the humanities will cause a loss in free thinking, and therefore a loss of democracy. Her argument is based off of her theory that without the humanities, citizens become soulless, mechanical, and profit-making machines. This theory is based off the notion that the humanities are continuing to beRead MoreThe Beginning Of The Humanities Sequence984 Words   |  4 PagesSince the beginning of the Humanities sequence, numerous themes have been expressed through various pieces of art and literature. A few of these themes have been so prevalent that they have flourished throughout the entire sequence of humanities classes. One of the major themes in particular is the idea of truth and where people have found truth in society. Some believe that truth comes from religion and higher powers, while others believe that knowing as many angles of a certain idea gains knowledgeRead MoreReflective Essay On Humanities1238 Words   |  5 PagesHumanities as a whole teach us a lot about people and their lives. For me humanities had been just another subject that I had to take as a prerequisite but now I find it very interesting to know about education, art, history and culture. People lives are revolving around humanities. The humanities are the source how people are getting along. Humanities connects people and place. The humanities make us to think creatively and also teach us to question about ourselves and our world.Read MoreThe Social Sciences And Humanities1114 Words   |  5 PagesThere seems to be a stigma present in our society, that social sciences and humanities are not as hard and require less work than science, technology, engineering, and mathematics, STEM, majors. In addition, women are still struggling to gain traction in STEM fields, and face gender bias quite frequently, as seen in the fact that women are only paid 77 cents for every dollar made by a man. We hypothesized that STEM majors would be rated as more academically competent than sociology majors. We alsoRead MoreReflection Paper On The Humanities Field1071 Words   |  5 Pagesout. Reflecting back on these individual papers helps to express what I have learned. The first paper that was written was the humanities essay. The humanities essay helped to provide an understanding of the artistic analysis of the artwork that we chose to write about. When the assignment was first assigned I thought it was going to be difficult, seeing that the humanities field is all about expressing your opinion and deconstructing the text for what it says and not how it does so. As I begun toRead MoreThe Importance Of Humanities : Starving For Wisdom1093 Words   |  5 Pagesimportance of Humanities: â€Å"Starving for Wisdom† In â€Å"Starving for Wisdom† by Nicholas Kristof, the author explains the importance of humanities in enriching people and finances. The humanities are learning about human culture with â€Å"literature, history, art music and philosophy† (Oxford Dictionaries). In summary, this essay explains the benefits of having the three modes of persuasion; ethos, pathos, logos and displays the impact and importance of the humanities. Decisions based on the humanities can haveRead MoreThe Importance Of Teaching Humanities And Arts1337 Words   |  6 PagesArts and Humanities Jenry Martin PHI103: Informal Logic Instructor: Stephen Krogh March 7, 2016 Ashford University My research is about the importance of teaching humanities and arts to kids. Humanities and art can provide understanding to children opening their minds and after my research, I can say I am in favor that children learn in early ages humanities and art. In this paper, I will provide both examples why kids should study them and why not. I will explain how do humanities and artRead MoreHumanities vs. Sciences Essay1938 Words   |  8 Pagesâ€Å"SCIENCE HAS BOMBS, and humanities have Britney Spears† (Kershner as cited in Purvis, 2004). This amusing comment, made during a professorial debate concerning which discipline was superior, epitomises the divide that exists between the humanities and sciences. Although the debate has its roots in the Industrial Revolution, in more recent times it was signalled by Snow’s (1959; 1964) discussion outlining the dysfunctional gulf that exists between the cultures. Essentially Snow was critical of theRead MoreEssay about The St udy of Anthropology and the Humanities1361 Words   |  6 Pages The humanities are a broad multidisciplinary field of study where its disciplines aren’t in just one department. Therefore, studying the humanities correlates to the study of anthropology. Simply put, anthropology is the study of humanity and the origins of human beings. Learning about the humanities can help those studying anthropology because the humanities looks into understanding and exploring the human condition. There is an idea of culture that is used to describe what humans do. AnthropologyRead MoreLoss of Humanities Should Not be a Sacrifice of Eduction Essay606 Words   |  3 PagesAs the reduction of the Humanities department begins to arise, many students lives are severely impacted. There are many positive and negative effects which come along with reducing funds in the Humanities departments. Though many individuals might contradict that reducing humanities may be a beneficial act for some , In my opinion it should not be lessened primarily because it can lead to malevolent mishaps. Decreasing humanities will result in excessive unemployment rates, superfluous amount of